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Experimental metal coating self-heals over scratches and scrapes to prevent corrosion

By Amanda Morris, Northwestern University

It's hard to believe that a tiny crack could take down a gigantic metal structure. But sometimes bridges collapse, pipelines rupture, and fuselages detach from airplanes due to hard-to-detect corrosion -- and some of that may have begun in small cracks, scratches, and dents.

A Northwestern University team has developed a new coating strategy for metal that self-heals within seconds when scratched, scraped, or cracked. The novel material could prevent these tiny defects from turning into localized corrosion, which can cause major structures to fail.

"Localized corrosion is extremely dangerous," said Jiaxing Huang, who led the research. "It is hard to prevent, hard to predict, and hard to detect, but it can lead to catastrophic failure."

When damaged by scratches and cracks, Huang's patent-pending system readily flows and reconnects to rapidly heal right before your eyes. The researchers demonstrated that the material can heal repeatedly -- even after scratching the exact same spot nearly 200 times in a row.

VIDEO: After being scratched, a new material coating self-heals right before your eyes. [Credit: Jiaxing Huang/Northwestern University]

The study was published Jan. 28, 2019, in Research, the first Science Partner Journal recently launched by the American Association for the Advancement of Science (AAAS) in collaboration with the China Association for Science and Technology (CAST). Huang is a professor of materials science and engineering in Northwestern's McCormick School of Engineering.

While a few self-healing coatings already exist, those systems typically work for nanometer- to micron-sized damages. To develop a coating that can heal larger scratches in the millimeter scale, Huang and his team looked to fluid.

"When a boat cuts through water, the water goes right back together," Huang said. "The ‘cut' quickly heals, because water flows readily. We were inspired to realize that fluids, such as oils, are the ultimate self-healing system."

But common oils flow too readily, Huang noted. So he and his team needed to develop a system with contradicting properties: fluidic enough to flow automatically but not so fluidic that it drips off the metal's surface.

The team met the challenge by creating a network of lightweight particles -- in this case graphene capsules -- to thicken the oil. The network fixes the oil coating, keeping it from dripping. But when the network is damaged by a crack or scratch, it releases the oil to flow readily and reconnect. Huang said the material can be made with any hollow, lightweight particle -- not just graphene.

"The particles essentially immobilize the oil film," Huang said. "So it stays in place."

The coating not only sticks, but it sticks well -- even under water and in harsh chemical environments, such as acid baths. Huang imagines that it could be painted onto bridges and boats that are naturally submerged under water as well as metal structures near leaked or spilled highly corrosive fluids. The coating can also withstand strong turbulence and stick to sharp corners without budging. When brushed onto a surface from under water, the coating goes on evenly without trapping tiny bubbles of air or moisture that can often lead to pin holes and corrosion.

"Self-healing microcapsule-thickened oil barrier coatings" was supported by the Office of Naval Research. Graduate student Alane Lim and Chenlong Cui, a former member of Huang's research group, served as the paper's co-first authors.

Published February 2019

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